孫さ〜ん! Stable Olympicenyl Radicals and Their π-Dimers https://t.co/NZVkmLizNp
Stable Olympicenyl Radicals and Their π-Dimers.
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Jun 2020 – Oct 2023Where it's discussed
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X / Twitter6 posts
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The discussions reveal a keen interest in the groundbreaking stability of the olympicenyl radicals and their unique dimer structures, with phrases like 'groundbreaking achievement' and references to specific techniques such as ESR spectroscopy. The tone reflects admiration and a desire to understand the broader implications, demonstrating a balanced engagement that recognizes the scientific significance without overly speculative claims.
Most discussions acknowledge the significance of the research, especially the stability and structural insights of the radicals, indicating a general agreement with the publication's importance.
The high interest score reflects enthusiasm among participants, with comments highlighting curiosity about the methods and implications of the findings.
Comments frequently mention specific details like the monomer-dimer equilibrium, ESR spectroscopy, and aromaticity, showing a moderate depth of engagement.
Participants consider the research to potentially influence future studies and understanding of radicals, though the discussions are more exploratory than conclusive.
Abstract in brief
- The article discusses the synthesis of two stable olympicenyl radical derivatives that have half-lives of 7 and 34 days in air, a significant achievement since such radicals are usually very reactive and short-lived.
- X-ray crystallography revealed unique dimers formed by head-to-tail structures with very close intermolecular distances, and these dimers were found to be in a singlet ground state with large energy gaps, confirmed by ESR spectroscopy.
- Studies showed that the monomers and their dimers exist in equilibrium and that dimer formation increases the local aromaticity of the molecules, as supported by both experimental techniques and theoretical calculations.
Top posts
Most liked on X and BlueskySunさん早速良い仕事.すごい. https://t.co/kvfY441PMg
Stable Olympicenyl Radicals and Their p-Dimers (Sun) J. Am. Chem. Soc. https://t.co/Xlj43Cvw6l
Stable Olympicenyl Radicals and Their π-Dimers https://t.co/z592WumiU9 タイムリーな話題になるはずだった報告だけど中身はおもしろい.こちらを本家オリンピセンにするべし
Stable Olympicenyl Radicals and Their π-Dimers https://t.co/eJ6v4qbm45 Trianguleneから6員環を1つ取った構造をOlympicenylと呼ぶのを初めて知った。
RT @yum_chem: Stable Olympicenyl Radicals and Their π-Dimers https://t.co/z592WumiU9 タイムリーな話題になるはずだった報告だけど中身はおもしろい.こちらを本家オリンピセンにするべし
All mentions
Examining Spin Inversion Independence in Entangled Radical Pairs
The content explores whether spin inversion can occur independently from hybridization during radical pair interactions, challenging traditional views on simultaneous entanglement and bonding processes.
Stable Olympicenyl Radicals and Their Dimers in Air
Stable Olympicenyl Radicals and Their π-Dimers https://t.co/eJ6v4qbm45 Trianguleneから6員環を1つ取った構造をOlympicenylと呼ぶのを初めて知った。
Stable Olympicenyl Radicals and Their p-Dimers (Sun) J. Am. Chem. Soc. https://t.co/Xlj43Cvw6l
Sunさん早速良い仕事.すごい. https://t.co/kvfY441PMg
RT @yum_chem: Stable Olympicenyl Radicals and Their π-Dimers https://t.co/z592WumiU9 タイムリーな話題になるはずだった報告だけど中身はおもしろい.こちらを本家オリンピセンにするべし
Stable Olympicenyl Radicals and Their π-Dimers https://t.co/z592WumiU9 タイムリーな話題になるはずだった報告だけど中身はおもしろい.こちらを本家オリンピセンにするべし
孫さ〜ん! Stable Olympicenyl Radicals and Their π-Dimers https://t.co/NZVkmLizNp