June 2020 PMID 32456437

Stable Olympicenyl Radicals and Their π-Dimers.

Qin Xiang, Jing Guo, Jun Xu, Shuaishuai Ding, Zhaoyang Li, Guangwu Li, Hoa Phan, Yanwei Gu, Yanfeng Dang, Zhanqiang Xu, Zongcheng Gong, Wenping Hu, Zebing Zeng, Jishan Wu, Zhe Sun

Mentions

8
Peak: 6 in Jun 2020
across 2 sources since Jun 2020

Extended reach

7,780
potential audience

Total likes

48

Video views

686

Mentions per month

Jun 2020 – Oct 2023

Where it's discussed

  • X / Twitter6 posts
  • YouTube2 videos

AI synopsis

What people are saying

The discussions reveal a keen interest in the groundbreaking stability of the olympicenyl radicals and their unique dimer structures, with phrases like 'groundbreaking achievement' and references to specific techniques such as ESR spectroscopy. The tone reflects admiration and a desire to understand the broader implications, demonstrating a balanced engagement that recognizes the scientific significance without overly speculative claims.

AgreementModerate agreement

Most discussions acknowledge the significance of the research, especially the stability and structural insights of the radicals, indicating a general agreement with the publication's importance.

InterestHigh interest

The high interest score reflects enthusiasm among participants, with comments highlighting curiosity about the methods and implications of the findings.

EngagementModerate engagement

Comments frequently mention specific details like the monomer-dimer equilibrium, ESR spectroscopy, and aromaticity, showing a moderate depth of engagement.

ImpactModerate impact

Participants consider the research to potentially influence future studies and understanding of radicals, though the discussions are more exploratory than conclusive.

Abstract in brief

  • The article discusses the synthesis of two stable olympicenyl radical derivatives that have half-lives of 7 and 34 days in air, a significant achievement since such radicals are usually very reactive and short-lived.
  • X-ray crystallography revealed unique dimers formed by head-to-tail structures with very close intermolecular distances, and these dimers were found to be in a singlet ground state with large energy gaps, confirmed by ESR spectroscopy.
  • Studies showed that the monomers and their dimers exist in equilibrium and that dimer formation increases the local aromaticity of the molecules, as supported by both experimental techniques and theoretical calculations.

Top posts

Most liked on X and Bluesky
T.M.Fukunaga
@tmfukunaga · X

孫さ〜ん! Stable Olympicenyl Radicals and Their π-Dimers https://t.co/NZVkmLizNp

Jun 10, 2020 · 5 likes · 794 followers View post →
Koji Harano 原野 幸治
@khng1980 · X

Sunさん早速良い仕事.すごい. https://t.co/kvfY441PMg

Jun 11, 2020 · 4 likes · 2,252 followers View post →
Ito Group NTU Singapore
@sgitolab · X

Stable Olympicenyl Radicals and Their p-Dimers (Sun) J. Am. Chem. Soc. https://t.co/Xlj43Cvw6l

Jun 15, 2020 · 4 likes · 1,666 followers View post →
Yasunori Matsui (松井康哲)
@yum_chem · X

Stable Olympicenyl Radicals and Their π-Dimers https://t.co/z592WumiU9 タイムリーな話題になるはずだった報告だけど中身はおもしろい.こちらを本家オリンピセンにするべし

Jun 11, 2020 · 4 likes · 1 share · 766 followers View post →
杉﨑 研司 (Kenji Sugisaki)
@Kenji_Sugisaki · X

Stable Olympicenyl Radicals and Their π-Dimers https://t.co/eJ6v4qbm45 Trianguleneから6員環を1つ取った構造をOlympicenylと呼ぶのを初めて知った。

Jun 24, 2020 · 3 likes · 1,187 followers View post →
自然学類の末裔 (リターンズ)
@sks_igp_fnbc · X

RT @yum_chem: Stable Olympicenyl Radicals and Their π-Dimers https://t.co/z592WumiU9 タイムリーな話題になるはずだった報告だけど中身はおもしろい.こちらを本家オリンピセンにするべし

Jun 11, 2020 · 1 share · 426 followers View post →

All mentions

杉﨑 研司 (Kenji Sugisaki)
@Kenji_Sugisaki · X

Stable Olympicenyl Radicals and Their π-Dimers https://t.co/eJ6v4qbm45 Trianguleneから6員環を1つ取った構造をOlympicenylと呼ぶのを初めて知った。

Jun 24, 2020 · 3 likes · 1,187 followers View post →
Ito Group NTU Singapore
@sgitolab · X

Stable Olympicenyl Radicals and Their p-Dimers (Sun) J. Am. Chem. Soc. https://t.co/Xlj43Cvw6l

Jun 15, 2020 · 4 likes · 1,666 followers View post →
Koji Harano 原野 幸治
@khng1980 · X

Sunさん早速良い仕事.すごい. https://t.co/kvfY441PMg

Jun 11, 2020 · 4 likes · 2,252 followers View post →
自然学類の末裔 (リターンズ)
@sks_igp_fnbc · X

RT @yum_chem: Stable Olympicenyl Radicals and Their π-Dimers https://t.co/z592WumiU9 タイムリーな話題になるはずだった報告だけど中身はおもしろい.こちらを本家オリンピセンにするべし

Jun 11, 2020 · 1 share · 426 followers View post →
Yasunori Matsui (松井康哲)
@yum_chem · X

Stable Olympicenyl Radicals and Their π-Dimers https://t.co/z592WumiU9 タイムリーな話題になるはずだった報告だけど中身はおもしろい.こちらを本家オリンピセンにするべし

Jun 11, 2020 · 4 likes · 1 share · 766 followers View post →
T.M.Fukunaga
@tmfukunaga · X

孫さ〜ん! Stable Olympicenyl Radicals and Their π-Dimers https://t.co/NZVkmLizNp

Jun 10, 2020 · 5 likes · 794 followers View post →