Nat Commun April 2023 PMID 37095089

Hidden chemical order in disordered BaNbMoO revealed by resonant X-ray diffraction and solid-state NMR.

Yuta Yasui, Masataka Tansho, Kotaro Fujii, Yuichi Sakuda, Atsushi Goto, Shinobu Ohki, Yuuki Mogami, Takahiro Iijima, Shintaro Kobayashi, Shogo Kawaguchi, Keiichi Osaka, Kazutaka Ikeda, Toshiya Otomo, Masatomo Yashima

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The discussions highlight the innovative methods used to uncover hidden atomic order, with phrases like 'new approach' and symbols of excitement such as 'breakthrough' and 'important discovery.' The tone emphasizes curiosity and the potential for significant advances in material science, reflecting shared recognition of the research's importance.

AgreementModerate agreement

Most discussions acknowledge the significance of the research in revealing hidden chemical order, showing general support for the findings.

InterestHigh interest

The discussions demonstrate high curiosity and enthusiasm about the new methods and implications of understanding disordered materials.

EngagementModerate engagement

Conversations show some depth with mentions of specific techniques like resonant X-ray diffraction and solid-state NMR, and their role in advancing materials science.

ImpactModerate impact

There is an appreciation that these findings could influence future research and technological applications in ion conductors and materials design.

Abstract in brief

This study reveals hidden chemical order in disordered BaNbMoO, a high ion conductor, using a combination of resonant X-ray diffraction, solid-state NMR, and first-principle calculations, overcoming limitations of traditional diffraction methods.
NMR directly showed that Mo atoms specifically occupy the M2 site near oxygen-deficient layers, and resonant X-ray diffraction quantified the occupancy of Mo at different sites, identifying a 50% presence at M2 and none at other sites.
These findings enhance understanding of how atomic arrangements affect material properties and could help in designing better ion conductors by uncovering hidden chemical order in similar disordered materials.]

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Revealing Hidden Chemical Order in Disordered Ba7Nb4MoO20 Using Advanced Techniques

This study uncovers hidden chemical order in disordered Ba7Nb4MoO20, a high ion conductor, through resonant X-ray diffraction and solid-state NMR, providing insights into atomic arrangements that impact material…

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