Publications by authors named "Genqiang Xue"

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Explorations of the nonheme high-valent iron-oxo landscape: crystal structure of a synthetic complex with an [FeIV2(μ-O)] diamond core relevant to the chemistry of sMMOH.
Gregory T Rohde, Genqiang Xue, Lawrence Que

Faraday Discuss· May 2022

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Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(IV) complexes.
Shengfa Ye, Genqiang Xue, Itana Krivokapic, Taras Petrenko, Eckhard Bill

Chem Sci· May 2015

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Spectroscopic and theoretical investigation of a complex with an [O═Fe(IV)-O-Fe(IV)═O] core related to methane monooxygenase intermediate Q.
Sebastian A Stoian, Genqiang Xue, Emile L Bominaar, Lawrence Que, Eckard Münck

J Am Chem Soc· January 2014

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Hydrogen-bonding effects on the reactivity of [X-Fe(III)-O-Fe(IV)═O] (X = OH, F) complexes toward C-H bond cleavage.
Genqiang Xue, Caiyun Geng, Shengfa Ye, Adam T Fiedler, Frank Neese

Inorg Chem· April 2013

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Nuclear resonance vibrational spectroscopic and computational study of high-valent diiron complexes relevant to enzyme intermediates.
Kiyoung Park, Caleb B Bell, Lei V Liu, Dong Wang, Genqiang Xue

Proc Natl Acad Sci U S A· April 2013

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1H-ENDOR evidence for a hydrogen-bonding interaction that modulates the reactivity of a nonheme Fe(IV)═O unit.
Muralidharan Shanmugam, Genqiang Xue, Lawrence Que, Brian M Hoffman

Inorg Chem· October 2012

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Evaluating the identity and diiron core transformations of a (μ-oxo)diiron(III) complex supported by electron-rich tris(pyridyl-2-methyl)amine ligands.
Loi H Do, Genqiang Xue, Lawrence Que, Stephen J Lippard

Inorg Chem· February 2012

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Substrate-triggered activation of a synthetic [Fe2(μ-O)2] diamond core for C-H bond cleavage.
Genqiang Xue, Alexander Pokutsa, Lawrence Que

J Am Chem Soc· October 2011

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Mössbauer, electron paramagnetic resonance, and density functional theory studies of synthetic S = 1/2 Fe(III)-O-Fe(IV)═O complexes. Superexchange-mediated spin transition at the Fe(IV)═O site.
Raymond F De Hont, Genqiang Xue, Michael P Hendrich, Lawrence Que, Emile L Bominaar

Inorg Chem· September 2010

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Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage.
Genqiang Xue, Raymond De Hont, Eckard Münck, Lawrence Que

Nat Chem· May 2010

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Observed enhancement of the reactivity of a biomimetic diiron complex by the addition of water - mechanistic insights from theoretical modeling.
Adam Johannes Johansson, Holger Noack, Per E M Siegbahn, Genqiang Xue, Lawrence Que

Dalton Trans· September 2009

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Mössbauer and DFT study of the ferromagnetically coupled diiron(IV) precursor to a complex with an Fe(IV)(2)O(2) diamond core.
Marlène Martinho, Genqiang Xue, Adam T Fiedler, Lawrence Que, Emile L Bominaar

J Am Chem Soc· April 2009

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Bio-inspired arene cis-dihydroxylation by a non-haem iron catalyst modeling the action of naphthalene dioxygenase.
Yan Feng, Chun-Yen Ke, Genqiang Xue, Lawrence Que

Chem Commun (Camb)· January 2009

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A synthetic precedent for the [FeIV2(mu-O)2] diamond core proposed for methane monooxygenase intermediate Q.
Genqiang Xue, Dong Wang, Raymond De Hont, Adam T Fiedler, Xiaopeng Shan

Proc Natl Acad Sci U S A· December 2007

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