Publications by authors named "Kenneth D Karlin"

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E
Experimental electronic structures of the Fe=O bond in S=1 heme vs. nonheme sites: Effect of the porphyrin ligand.
Augustin Braun, Leland B Gee, Max D J Waters, Anex Jose, Michael L Baker, Kenneth D Karlin

Proc Natl Acad Sci U S A· February 2025

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Reactivity of a heterobinuclear heme-peroxo-Cu complex with -substituted catechols shows a p -dependent change in mechanism.
Sanjib Panda, Suzanne M Adam, Hai Phan, Patrick J Rogler, Pradip Kumar Hota, Kenneth D Karlin

Chem Sci· January 2025

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Dioxygenase Chemistry in Nucleophilic Aldehyde Deformylations Utilizing Dicopper O-Derived Peroxide Complexes.
Pradip Kumar Hota, Sanjib Panda, Hai Phan, Bohee Kim, Maxime A Siegler, Kenneth D Karlin

J Am Chem Soc· August 2024

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Intramolecular Phenolic H-Atom Abstraction by a NArOH Ligand-Supported (μ-η:η-Peroxo)dicopper(II) Species Relevant to the Active Site Function of oxy-Tyrosinase.
Sanjib Panda, Hai Phan, Eleanor M Dunietz, Magdalene T Brueggemeyer, Pradip Kumar Hota, Kenneth D Karlin

J Am Chem Soc· June 2024

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Synthetic Copper-(Di)oxygen Complex Generation and Reactivity Relevant to Copper Protein O-Processing.
Kenneth D Karlin, Pradip Kumar Hota, Bohee Kim, Sanjib Panda, Hai Phan

Bull Jpn Soc Coord Chem· June 2024

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Coordination Variations within Binuclear Copper Dioxygen-Derived (Hydro)Peroxo and Superoxo Species; Influences upon Thermodynamic and Electronic Properties.
Pradip Kumar Hota, Anex Jose, Sanjib Panda, Eleanor M Dunietz, Austin E Herzog, Kenneth D Karlin

J Am Chem Soc· May 2024

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Heme-copper and Heme O-derived synthetic (bioinorganic) chemistry toward an understanding of cytochrome c oxidase dioxygen chemistry.
Sanjib Panda, Hai Phan, Kenneth D Karlin

J Inorg Biochem· December 2023

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Ligand-Copper(I) Primary O-Adducts: Design, Characterization, and Biological Significance of Cupric-Superoxides.
Bohee Kim, Kenneth D Karlin

Acc Chem Res· August 2023

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Fenton-like Chemistry by a Copper(I) Complex and HO Relevant to Enzyme Peroxygenase C-H Hydroxylation.
Bohee Kim, Magdalene T Brueggemeyer, Wesley J Transue, Younwoo Park, Jaeheung Cho, Kenneth D Karlin

J Am Chem Soc· May 2023

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Reductive Coupling of Nitric Oxide by Cu(I): Stepwise Formation of Mono- and Dinitrosyl Species to a Cupric Hyponitrite Intermediate.
Mayukh Bhadra, Therese Albert, Alicja Franke, Verena Josef, Ivana Ivanović-Burmazović, Kenneth D Karlin

J Am Chem Soc· February 2023

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Concluding remarks: discussion on natural and artificial enzymes including synthetic models.
Kenneth D Karlin, Pradip K Hota, Bohee Kim

Faraday Discuss· May 2022

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End-On Copper(I) Superoxo and Cu(II) Peroxo and Hydroperoxo Complexes Generated by Cryoreduction/Annealing and Characterized by EPR/ENDOR Spectroscopy.
Roman Davydov, Austin E Herzog, Richard J Jodts, Kenneth D Karlin, Brian M Hoffman

J Am Chem Soc· January 2022

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Proton Relay in Iron Porphyrins for Hydrogen Evolution Reaction.
Sarmistha Bhunia, Atanu Rana, Shabnam Hematian, Kenneth D Karlin, Abhishek Dey

Inorg Chem· September 2021

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Ferric Heme Superoxide Reductive Transformations to Ferric Heme (Hydro)Peroxide Species: Spectroscopic Characterization and Thermodynamic Implications for H-Atom Transfer (HAT).
Hyun Kim, Patrick J Rogler, Savita K Sharma, Andrew W Schaefer, Edward I Solomon, Kenneth D Karlin

Angew Chem Int Ed Engl· March 2021

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A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity.
Mayukh Bhadra, Wesley J Transue, Hyeongtaek Lim, Ryan E Cowley, Jung Yoon C Lee, Kenneth D Karlin

J Am Chem Soc· March 2021

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Kβ X-ray Emission Spectroscopy as a Probe of Cu(I) Sites: Application to the Cu(I) Site in Preprocessed Galactose Oxidase.
Hyeongtaek Lim, Michael L Baker, Ryan E Cowley, Sunghee Kim, Mayukh Bhadra, Kenneth D Karlin

Inorg Chem· November 2020

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Heme-Fe Superoxide, Peroxide and Hydroperoxide Thermodynamic Relationships: Fe-O Complex H-Atom Abstraction Reactivity.
Hyun Kim, Patrick J Rogler, Savita K Sharma, Andrew W Schaefer, Edward I Solomon, Kenneth D Karlin

J Am Chem Soc· February 2020

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Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O-H and C-H Substrates.
Daniel E Diaz, David A Quist, Austin E Herzog, Andrew W Schaefer, Ioannis Kipouros, Kenneth D Karlin

Angew Chem Int Ed Engl· December 2019

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Copper(I) Complex Mediated Nitric Oxide Reductive Coupling: Ligand Hydrogen Bonding Derived Proton Transfer Promotes NO Release.
Gayan B Wijeratne, Mayukh Bhadra, Maxime A Siegler, Kenneth D Karlin

J Am Chem Soc· November 2019

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Heme-Cu Binucleating Ligand Supports Heme/O and Fe-Cu/O Reactivity Providing High- and Low-Spin Fe-Peroxo-Cu Complexes.
Hyun Kim, Savita K Sharma, Andrew W Schaefer, Edward I Solomon, Kenneth D Karlin

Inorg Chem· November 2019

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Dimethylanilinic -Oxides and Their Oxygen Surrogacy Role in the Formation of a Putative High-Valent Copper-Oxygen Species.
Daniel E Diaz, Mayukh Bhadra, Kenneth D Karlin

Inorg Chem· October 2019

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Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O and NO and Mechanistic Insights into Metal-Mediated Peroxynitrite Decomposition.
Jeffrey J Liu, Maxime A Siegler, Kenneth D Karlin, Pierre Moënne-Loccoz

Angew Chem Int Ed Engl· August 2019

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Ligand Identity-Induced Generation of Enhanced Oxidative Hydrogen Atom Transfer Reactivity for a Cu(O) Complex Driven by Formation of a Cu(OOH) Compound with a Strong O-H Bond.
David A Quist, Melanie A Ehudin, Andrew W Schaefer, Gregory L Schneider, Edward I Solomon, Kenneth D Karlin

J Am Chem Soc· August 2019

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Enhanced Rates of C-H Bond Cleavage by a Hydrogen-Bonded Synthetic Heme High-Valent Iron(IV) Oxo Complex.
Melanie A Ehudin, David A Quist, Kenneth D Karlin

J Am Chem Soc· August 2019

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Formation and Reactivity of New Isoporphyrins: Implications for Understanding the Tyr-His Cross-Link Cofactor Biogenesis in Cytochrome Oxidase.
Melanie A Ehudin, Laura Senft, Alicja Franke, Ivana Ivanović-Burmazović, Kenneth D Karlin

J Am Chem Soc· July 2019

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