Publications by authors named "Pablo Espinet"

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Opposite Effects of Added AsPh Reveal a Drastic Mechanistic Switch in Rh/Au Transmetalations via Rh-Au Bonded Intermediates.
Marconi N Peñas-Defrutos, Camino Bartolomé, Max García-Melchor, Pablo Espinet

Inorg Chem· July 2025

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Solid state luminescence of phosphine-EWO ligands with fluorinated chalcone skeletons and their PdX complexes: metal-promoted phosphorescence enhancement.
Jaime Ponce-de-León, Marconi N Peñas-Defrutos, Andrea Vélez, Gabriel Aullón, Pablo Espinet

Dalton Trans· March 2023

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Intimate relationship between C-I reductive elimination, aryl scrambling and isomerization processes in Au(III) complexes.
Sara Fernández-Moyano, Guillermo Marcos-Ayuso, Marconi N Peñas-Defrutos, Camino Bartolomé, Pablo Espinet

Chem Commun (Camb)· February 2023

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Problematic Ar-Alkynyl Coupling with Fluorinated Aryls. From Partial Success with Alkynyl Stannanes to Efficient Solutions via Mechanistic Understanding of the Hidden Complexity.
Guillermo Marcos-Ayuso, Marconi N Peñas-Defrutos, Ana M Gallego, Max García-Melchor, Jesús M Martínez-Ilarduya, Pablo Espinet

J Am Chem Soc· January 2023

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Pd/Cu bimetallic catalysis to access highly fluorinated biaryls from aryl halides and fluorinated arenes.
Jaime Ponce-de-León, Guillermo Marcos-Ayuso, Juan A Casares, Pablo Espinet

Chem Commun (Camb)· March 2022

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Selective synthesis of fluorinated biaryls by [MCl(PhPEWO-F)] (M = Ni, Pd) catalysed Negishi cross-coupling.
Jaime Ponce-de-León, Pablo Espinet

Chem Commun (Camb)· October 2021

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Expanding the Concepts Trans Influence and Back-Donation: Hybrid and Side Donations in [Cp*M(L)XY] (M = Rh, Ir) Complexes with CO, CN, and CNR Ligands. A Window to Cis Influence.
Sara Fernández-Moyano, Marconi N Peñas-Defrutos, Camino Bartolomé, Pablo Espinet

Inorg Chem· September 2021

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Easy wide scope access to luminescent fluorophosphoranes.
Jaime Ponce-de-León, Rebeca Infante, Pablo Espinet

Chem Commun (Camb)· June 2021

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Striking ligand-disproportionative Cl/aryl scrambling in a simple Au(III) system. Solvent role, driving forces and mechanisms.
Sara Fernández-Moyano, Marconi N Peñas-Defrutos, Camino Bartolomé, Pablo Espinet

Chem Commun (Camb)· January 2021

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Ranking Ligands by Their Ability to Ease (CF)NiL → NiL + (CF) Coupling versus Hydrolysis: Outstanding Activity of PEWO Ligands.
Jaime Ponce-de-León, Estefania Gioria, Jesús M Martínez-Ilarduya, Pablo Espinet

Inorg Chem· December 2020

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Fluorinated vs Nonfluorinated PR(biaryl) Ligands and Their [AuCl(L)] Complexes: Synthesis, X-ray Structures, and Computational Study of Weak Interactions. Bond, No Bond, and Beyond.
Jaime Ponce-de-León, Rebeca Infante, Marı A Pérez-Iglesias, Pablo Espinet

Inorg Chem· November 2020

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Fluorescent perylenylpyridine complexes: an experimental and theoretical study.
J Emilio Expósito, Gabriel Aullón, Manuel Bardají, Jesús A Miguel, Pablo Espinet

Dalton Trans· October 2020

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Striking Increase in Hole Mobility upon Metal Coordination to Triphenylene Schiff Base Semiconducting Multicolumnar Mesophases.
Estela de Domingo, César L Folcia, Josu Ortega, Jesús Etxebarria, Roberto Termine, Pablo Espinet

Inorg Chem· August 2020

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Experimental study of speciation and mechanistic implications when using chelating ligands in aryl-alkynyl Stille coupling.
Ana M Gallego, Marconi N Peñas-Defrutos, Guillermo Marcos-Ayuso, Jose M Martin-Alvarez, Jesús M Martínez-Ilarduya, Pablo Espinet

Dalton Trans· August 2020

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4-Pyridylisocyanide gold(i) and gold(i)-plus-silver(i) luminescent and mechanochromic materials: the silver role.
Verónica Conejo-Rodríguez, Marconi N Peñas-Defrutos, Pablo Espinet

Dalton Trans· July 2019

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dd RhAu interactions in Rh 2,6-xylylisocyanide complexes with [Au(CN)]: bond analysis and crystal effects.
Verónica Conejo-Rodríguez, Marconi N Peñas-Defrutos, Pablo Espinet

Chem Commun (Camb)· April 2019

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Rh Ar/Au Ar' Transmetalation: A Case of Group Exchange Pivoting on the Formation of M-M' Bonds through Oxidative Insertion.
Marconi N Peñas-Defrutos, Camino Bartolomé, Max García-Melchor, Pablo Espinet

Angew Chem Int Ed Engl· March 2019

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Highly enantioselective addition of dimethylzinc to fluorinated alkyl ketones, and the mechanism behind it.
Tomaz Neves-Garcia, Andrea Vélez, Jesús M Martínez-Ilarduya, Pablo Espinet

Chem Commun (Camb)· October 2018

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Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C-Au Bonds in [AuRL] Complexes.
María Pérez-Iglesias, Pablo Espinet, Juan A Casares

Inorg Chem· September 2018

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Triphenylene-Imidazolium Salts and Their NHC Metal Complexes, Materials with Segregated Multicolumnar Mesophases.
Ana B Miguel Coello, Manuel Bardají, Silverio Coco, Bertrand Donnio, Benoît Heinrich, Pablo Espinet

Inorg Chem· April 2018

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Polymer [Pd(CHSOCHMe)], a precursor to remarkably stable Pd organometallics.
Celeste Pérez-Briso, Ana M Gallego, Jose M Martín-Alvarez, Jesús M Martínez-Ilarduya, Pablo Espinet

Dalton Trans· June 2017

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Promoting Difficult Carbon-Carbon Couplings: Which Ligand Does Best?
Estefanía Gioria, Juan Del Pozo, Jesús M Martínez-Ilarduya, Pablo Espinet

Angew Chem Int Ed Engl· October 2016

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In Situ Generation of ArCu from CuF2 Makes Coupling of Bulky Aryl Silanes Feasible and Highly Efficient.
Juan delPozo, Juan A Casares, Pablo Espinet

Chemistry· March 2016

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Higher fluorescence in platinum(iv) orthometallated complexes of perylene imine compared with their platinum(ii) or palladium(ii) analogues.
J Emilio Expósito, Marta Álvarez-Paíno, Gabriel Aullón, Jesús A Miguel, Pablo Espinet

Dalton Trans· September 2015

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H-Bonded adducts of [2,4,6-{(C10H21O)3C6H2NH}3C3N3] with [LnM{PPh2(C6H4CO2H)}] displaying columnar mesophases at room temperature.
Ana B Miguel-Coello, Manuel Bardají, Silverio Coco, Bertrand Donnio, Benoît Heinrich, Pablo Espinet

Inorg Chem· October 2014

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