Publications by authors named "Philip Ash"

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Cyanophenylalanine as an Infrared Probe for Iron-Sulfur Cluster Redox State in Multicenter Metalloenzymes.
Zehui Duan, Jiaao Wei, Stephen B Carr, Miguel Ramirez, Rhiannon M Evans, Philip A Ash

Chembiochem· July 2025

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Comprehensive structural, infrared spectroscopic and kinetic investigations of the roles of the active-site arginine in bidirectional hydrogen activation by the [NiFe]-hydrogenase 'Hyd-2' from .
Rhiannon M Evans, Stephen E Beaton, Patricia Rodriguez Macia, Yunjie Pang, Kin Long Wong, Philip A Ash

Chem Sci· August 2023

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Electrochemical experiments define potentials associated with binding of substrates and inhibitors to nitrogenase MoFe protein.
Ting Chen, Philip A Ash, Lance C Seefeldt, Kylie A Vincent

Faraday Discuss· July 2023

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Electron transfer, spectroscopy and theory: general discussion.
Anjali Anilkumar, Philip Ash, Akhil R Chakravarty, Peter Comba, Serena DeBeer

Faraday Discuss· May 2022

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Natural and artificial enzymes and medicinal aspects: general discussion.
Philip Ash, Akhil R Chakravarty, Peter Comba, Abhishek Dey, Debabrata Goswami

Faraday Discuss· May 2022

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The crystalline state as a dynamic system: IR microspectroscopy under electrochemical control for a [NiFe] hydrogenase.
Philip A Ash, Sophie E T Kendall-Price, Rhiannon M Evans, Stephen B Carr, Amelia R Brasnett

Chem Sci· October 2021

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Electrochemical control of [FeFe]-hydrogenase single crystals reveals complex redox populations at the catalytic site.
Simone Morra, Jifu Duan, Martin Winkler, Philip A Ash, Thomas Happe

Dalton Trans· September 2021

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Redox state and photoreduction control using X-ray spectroelectrochemical techniques - advances in design and fabrication through additive engineering.
Stephen Peter Best, Victor A Streltsov, Christopher Thomas Chantler, Wangzhe Li, Philip A Ash

J Synchrotron Radiat· March 2021

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Unifying Activity, Structure, and Spectroscopy of [NiFe] Hydrogenases: Combining Techniques To Clarify Mechanistic Understanding.
Philip A Ash, Sophie E T Kendall-Price, Kylie A Vincent

Acc Chem Res· November 2019

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Dioxygen controls the nitrosylation reactions of a protein-bound [4Fe4S] cluster.
Daniel B Grabarczyk, Philip A Ash, William K Myers, Erin L Dodd, Kylie A Vincent

Dalton Trans· October 2019

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Mechanistic Exploitation of a Self-Repairing, Blocked Proton Transfer Pathway in an O-Tolerant [NiFe]-Hydrogenase.
Rhiannon M Evans, Philip A Ash, Stephen E Beaton, Emily J Brooke, Kylie A Vincent

J Am Chem Soc· August 2018

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Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase.
Philip A Ash, Ricardo Hidalgo, Kylie A Vincent

J Vis Exp· December 2017

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Vibrational Spectroscopic Techniques for Probing Bioelectrochemical Systems.
Philip A Ash, Kylie A Vincent

Adv Biochem Eng Biotechnol· September 2017

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Electrochemical CO Oxidation at Platinum on Carbon Studied through Analysis of Anomalous in Situ IR Spectra.
Ian J McPherson, Philip A Ash, Lewys Jones, Aakash Varambhia, Robert M J Jacobs

J Phys Chem C Nanomater Interfaces· August 2017

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Proton Transfer in the Catalytic Cycle of [NiFe] Hydrogenases: Insight from Vibrational Spectroscopy.
Philip A Ash, Ricardo Hidalgo, Kylie A Vincent

ACS Catal· April 2017

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Enzymes as modular catalysts for redox half-reactions in H2-powered chemical synthesis: from biology to technology.
Holly A Reeve, Philip A Ash, HyunSeo Park, Ailun Huang, Michalis Posidias

Biochem J· January 2017

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Nanopores: general discussion.
Andrew Mount, Minkyung Kang, David Fermin, Tim Albrecht, J Gooding, Philip A Ash

Faraday Discuss· December 2016

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Formate adsorption on Pt nanoparticles during formic acid electro-oxidation: insights from in situ infrared spectroscopy.
Ian J McPherson, Philip A Ash, Robert M J Jacobs, Kylie A Vincent

Chem Commun (Camb)· October 2016

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Synchrotron-Based Infrared Microanalysis of Biological Redox Processes under Electrochemical Control.
Philip A Ash, Holly A Reeve, Jonathan Quinson, Ricardo Hidalgo, Tianze Zhu

Anal Chem· July 2016

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Electrochemical and Infrared Spectroscopic Studies Provide Insight into Reactions of the NiFe Regulatory Hydrogenase from Ralstonia eutropha with O2 and CO.
Philip A Ash, Juan Liu, Nathan Coutard, Nina Heidary, Marius Horch

J Phys Chem B· October 2015

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Discovery of Dark pH-Dependent H(+) Migration in a [NiFe]-Hydrogenase and Its Mechanistic Relevance: Mobilizing the Hydrido Ligand of the Ni-C Intermediate.
Bonnie J Murphy, Ricardo Hidalgo, Maxie M Roessler, Rhiannon M Evans, Philip A Ash

J Am Chem Soc· July 2015

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Infrared Spectroscopy During Electrocatalytic Turnover Reveals the Ni-L Active Site State During H2 Oxidation by a NiFe Hydrogenase.
Ricardo Hidalgo, Philip A Ash, Adam J Healy, Kylie A Vincent

Angew Chem Int Ed Engl· June 2015

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Carbon electrode interfaces for synthesis, sensing and electrocatalysis: general discussion.
Yury Gogotsi, Richard McCreery, Stephen M Lyth, Robert Dryfe, John Foord, Philip A Ash

Faraday Discuss· May 2015

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Comparison of carbon materials as electrodes for enzyme electrocatalysis: hydrogenase as a case study.
Jonathan Quinson, Ricardo Hidalgo, Philip A Ash, Frank Dillon, Nicole Grobert

Faraday Discuss· May 2015

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Highlights from Faraday Discussion 172: Carbon in electrochemistry, Sheffield, UK, July 2014.
Boris Dyatkin, Philip A Ash, Surbhi Sharma

Chem Commun (Camb)· February 2015

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